Solutions, Coatings, Polyurea Coating

Wanhua Two-component Spray Polyurea Material System & Technology

Two-component Spray Polyurea Material System

01 Materials

Market Classification

Other Common Names:

  • Spray Quick-curing Polyurea
  • Manual Application Polyurea
  • Fast-drying Polyurea
  • Slow-drying Polyurea

Polyurea Classification: Two-component (Spray Type, Brush Type) / One-component (Brush Type)

1.1 Brief Introduction to Two-component Spray Polyurea Material System

Spray Polyurea Elastomer (SPUA) technology is a new type of environment-friendly construction technology developed in the United States in the 1980s. It is widely used in waterproofing, anti-corrosion, wear-resistance and other fields.
 
This technology organically integrates new materials, new equipment and new processes, breaking through the limitations of traditional environment-friendly coating technologies.
 
China began to introduce and independently develop this technology in the mid-1990s, and it has now been applied in a number of large-scale engineering projects.
 
Landmark Projects: Beijing-Tianjin Intercity Railway (2006), Beijing-Shanghai High-Speed Railway (2008)
Spray Polyurea Elastomer

Features and Limitations

Features

  1. Fast curing: gels in 10 seconds and reaches walk-on strength in 10 minutes. It can be spray-formed on any curved, inclined or vertical surface.
  2. High solid content with zero VOCs, making it environmentally friendly.
  3. Achieves the required thickness in a single application, eliminating the drawbacks of multiple-coat construction.
  4. Excellent physical properties, including high tensile strength, high elongation, chemical resistance, wear resistance and impact resistance.
  5. The coating is dense and seamless, providing skin-like protection with exceptional results.
  6. High construction efficiency: the daily construction area can exceed 500 square meters.
 

Limitations

  1. Requires specialized spraying equipment.
  2. Demands rigorous substrate preparation.
  3. Needs professional construction personnel.
  4. Involves high material and construction costs.
Features and Limitations

Differences Between Polyurea and Polyurethane

Differences Between Polyurea and Polyurethane

1.2 Main and Auxiliary Materials of Polyurea – A Systematic Understanding of Polyurea

Main and Auxiliary Materials of Polyurea – A Systematic Understanding of Polyurea

1.3 Polyurea Tensile Test – Understanding Polyurea Through Testing

Routine Tests – Understanding Polyurea Through Testing

The Most Common Adhesion Test – Pull-off Test

The Most Common Adhesion Test – Pull-off Test

Pull-off Test on Steel Substrates –  until the coating fails.

Pull-off Test on Steel Substrates – Coating Failure Shall Be Mandatory

Adhesion Testing Equipment for Construction Sites

On-site Adhesion Test Equipment

Note: Data measured by the pull-off method (vertical pull-off test) can be misleading. Even with poor adhesion, qualified values can still be obtained, for example, if the cutting around the pull-off dolly is incomplete.

The Most Reliable Adhesion Test – Peeling Test for Flexible Materials

The Most Reliable Adhesion Test – Peeling Test for Flexible Materials

A pair of pliers can be used on-site to simulate the peeling test by tearing

Temperature Resistance – Low-Temperature Flexibility and High-Temperature Water Immersion

Low-temperature flexibility at -40℃
High-temperature water immersion at 70℃: Blistering Upper limit temperature for liquid media: 60℃

Low-temperature flexibility at -40℃

High-temperature water immersion at 70℃: Blistering

Upper limit temperature for liquid media: 60℃

Chemical Resistance / Corrosion Resistance

Chemical Medium Resistance (23℃ / 1 year)

Medium namesSoaking resultsMedium NamesSoaking results
10% acetic acidVery goodSeawaterVery good
10% hydrochloric acidVery goodXyleneNot recommended
30% sulfuric acidVery goodCrude OilVery good
10% phosphoric acidGood color changeGasolineNot recommended
20% ammonia waterVery goodDieselVery good
20% potassium hydroxideGood color changeEngine OilVery good
50% sodium hydroxideVery goodHydraulic OilVery good
Saturated brineVery goodAmmonium NitrateVery good

Chemical Resistance Verification – Corrosion Resistance (1 Year)

Chemical Resistance Verification – Corrosion Resistance (1 Year)
Serial NumberTensile strength (MPa)Elongation at break (%)
10% Sulfuric Acid29.1466.5
20% Sulfuric Acid29459.7
30% Sulfuric Acid27.7448.6
50% Sodium Hydroxide29.9463.6

Wear Resistance

Polyurea abrasion resistance test

Erosion Resistance Data

Erosion Resistance Data

Erosion Resistance of Two-component Spray Polyurea

Erosion Resistance of One-component Polyurea

Material TypesWeight loss gWear rate (g/cm²·h)Wear volume (cm³)Surface Condition
Abrasion-resistant polyurea elastomer2.50.0272.45The coating surface remained largely unchanged, with no visible grooves.
Secondary aggregate concrete with limestone f28 = 66.5 MPa4140.44159.2The inner wall of the specimen showed numerous grooves and other defects after grinding.
Secondary aggregate concrete with granite f28 = 65.6 MPa980.10437.7The inner wall of the specimen showed numerous grooves and other defects after grinding.

1.4 Common Standards for Spray Polyurea Materials

GB/T 23446-2009 Spray Polyurea Waterproof Coating
JC/T 2252-2014 Primers and Putties for Spray Polyurea
HG/T 3831-2006 Spray Polyurea Protective Materials

GB/T 23446-2009

Spray Polyurea Waterproof Coating

JC/T 2252-2014

Primers and Putties for Spray Polyurea

HG/T 3831-2006

Spray Polyurea Protective Materials

GB/T 23446-2009

The Most Important Standard for Material Properties

JC/T 2252-2014

Indicators Affecting Durability – Low Values
 
Personal Opinion:
 
Peel strength ≥ 12 N/mm
 
Adhesion retention rate ≥ 90% (minimum 3 months)

1.5 Industry Pain Points

Loss of Adhesion

Industry Pain Points
Industry Pain Points
Industry Pain Points

Routine

Immersion Damage

Freeze-Thaw Damage

Plasticization effect of water and damage to adhesive hydrogen bonds (chemical bonds)

1.6 Reliability of Wanhua Polyurea

Persistence of Adhesion Under Long-term Immersion

Reliability of Wanhua Polyurea
Reliability of Wanhua Polyurea

180° Peel Test After 3 Months of Immersion

1 Year of Immersion

Destructive Test – Persistence of Adhesion

Destructive Test
Destructive Test

Two-component Spray Polyurea Material System

02 Application

Wanhua Polyurea Application Distribution
 
  • Concrete Protection: 70%
  • Steel Structure Anticorrosion: 10%
  • Roof Waterproofing: 10%
  • Wear-resistant Lining: 5%
  • Others: 5%

Signature Projects – Gaining Worldwide Attention

Bridge Deck of Beijing-Shanghai High-Speed Railway
 
It remains the world’s largest-scale polyurea waterproofing project to date, with a total consumption of polyurea coatings exceeding 20,000 tons. Adopting ballastless tracks, the Beijing-Shanghai High-Speed Railway imposes stringent requirements on waterproofing layers: they must not only fulfill the basic performance of anti-seepage and crack resistance, but also withstand the impacts caused by high-speed, heavy-haul, and alternating loads during train operations. Polyurea, reputed as the "King of Coatings", has achieved remarkable application in this project.
Bridge Deck of Beijing-Shanghai High-Speed Railway

Transportation Engineering

Transportation Engineering

Concrete roof waterproofing

Concrete roof waterproofing

Integrated thermal insulation and waterproofing, old house renovation

Integrated thermal insulation and waterproofing, old house renovation

Oceanarium Pool Waterproofing

Oceanarium Pool Waterproofing

Stadium stands

Stadium stands

Hydraulic engineering - grinding, waterproofing, seepage prevention

Hydraulic engineering - grinding, waterproofing, seepage prevention

Hydraulic grinding

Hydraulic grinding

Audio equipment and vehicle wear resistance

Audio equipment and vehicle wear resistance

Mining wear-resistant

Mining wear-resistant

Pipeline corrosion protection

Pipeline corrosion protection

Waterproofing and corrosion protection for sewage treatment ponds

Waterproofing and corrosion protection for sewage treatment ponds

Chemical corrosion protection

Chemical corrosion protection

petroleum energy

petroleum energy

Tank corrosion protection

Tank corrosion protection

Environmental Protection Industry - High-Density Tanks, Sludge Thickening Tanks

Environmental Protection Industry - High-Density Tanks, Sludge Thickening Tanks

Aquaculture industry

Aquaculture industry

Fenders and military industry

Fenders and military industry

Two-component Spray Polyurea Material System

03 Equipment

3.1 Concrete Substrate Treatment Equipment

Concrete Substrate Treatment Equipment

3.2 Metal Substrate Treatment Equipment

Metal Substrate Treatment Equipment
Differences in corrosion rates of different surface treatment coatings
Serial NumberTreatment methodsRust and corrosion status of the coating
1No rust removal60%
2Manual rust removal20%
3Acid pickling15%
4SandblastingOnly a few rust spots
Coating damage period
Serial NumberTreatment methodsRepainting deadline/year
1Air blowing, wire brush cleaning3
2Flame purification5
3Acid pickling, phosphoric acid impregnation5.5
4Sandblasting or shot blasting7

3.3 Primer spraying equipment

Primer spraying equipment

Pneumatic pumps are suitable for low-viscosity or solvent-based spraying.

Hydraulic pumps are suitable for high-viscosity or solvent-free spraying.

spray gun

Spray painting video

Spray painting video

3.4 Putty Spraying Equipment

3.4 Putty Spraying Equipment
Putty Spraying Equipment

Recommendation: Use equipment spraying as the primary method, supplemented by manual scraping and smoothing.

3.5 Introduction to Two-Component Spraying Polyurea Material Equipment

Introduction to Two-Component Spraying Polyurea Material Equipment

Two-component high-pressure airless sprayer

Two-component high-pressure airless sprayer

Graco H-xp3 Basic Parameters

Maximum Output Pressure: 3500 Psi (240 bar)
Maximum Output Flow Rate: 2.8 gallons/min (10.6 liters/min)
Maximum Heating Power: 20 kW
Operating Voltage: 380V
Maximum Heating Temperature: 88℃
Maximum Supported Pipe Length: 123 meters
Weight: 271 kg

During Spraying:

Component A Heating Temperature: 60-65℃

Component B Heating Temperature: 60-65℃

Pipe Heating Temperature: 60-65℃

Spraying Static Pressure: 2000-2500 Psi

AP spray gun and MP spray gun

AP spray gun and MP spray gun

AP = Air-Purge / Air Self-Cleaning
MP = Mechanical-Purge Spray Gun / Mechanical Self-Cleaning Spray Gun

AP spray gun

AP spray gun

3.6 Personnel and Equipment Configuration

Serial NumberProcessToolsPersonnelRemarks
1Substrate preparation (cleaning, grinding, dust removal)Angle grinders, floor grinders, high-pressure water guns, sandblasting machines, shot blasting machines, grooving machines, vacuum cleaners, etc.4-6 peopleScaffolding, suspended platforms, and elevators will be determined on a case-by-case basis.
2Substrate sealingScrew pump sprayers, high-pressure airless sprayers/pneumatic pump sprayers, electronic scales, handheld mixers, etc.4-6 peopleLow-value consumables such as scrapers and rollers will be determined on a case-by-case basis.
3Polyurea sprayingPolyurea sprayers, air compressors, refrigerated dryers, pneumatic mixers, etc.3-6 peopleProtective consumables will be determined on a case-by-case basis.

In the construction of large projects, there are specialized teams to carry out tasks such as scaffolding/suspended platform erection/dismantling, base layer grinding, base layer sealing, and polyurea spraying.

Two-component Spray Polyurea Material System

04 Process

4.1 Engineering Application Technical Specifications

Engineering Application Technical Specifications

HG/T 20273-2011

Technical Specification for Coating Engineering of Spray-applied Polyurea Protective Materials

JGJ/T 200-2010

Technical Specification for Sprayed Polyurea Waterproofing Engineering

T/CECS 679-2020

Technical Specification for Polyurea Coating Application

4.2 Detailed Construction Drawings

Detailed Construction Drawings
Detailed Construction Drawings

4.3 External and Internal Angles

External and Internal Angles

 

Specific application method: Grind the corners to create a rounded shape, and apply a thicker layer during spraying.

 

 

 

Specific application method: Use putty/mortar to create rounded corners, and apply a thicker layer during spraying.

4.4 Pretreatment of Dead Seams

Pretreatment of Dead Seams

Chisel a U-shaped or V-shaped groove along the crack, approximately 10cm wide at the top, and then fill the groove with sealant.

Sealing materials include: cement mortar, epoxy mortar, elastic epoxy mortar, polymer cement mortar, etc.

For steel reinforcement corrosion: remove rust from the steel reinforcement, perform rust prevention treatment, and then fill the crack.

Epoxy grouting can be used to seal leaks according to customer requirements.

4.5 Pre-treatment of open seams

Pre-treatment of open seams

For a live joint, a U-shaped groove is cut along the crack's direction. A layer of non-adhesive material is placed at the bottom of the groove, followed by filling with an elastic sealant that adheres to both sides of the groove. This allows the sealant to deform freely along the entire width of the groove, preventing tearing forces from pulling the sealant apart when the crack deforms.

Epoxy grouting is used for leak sealing according to customer requirements.

4.6 Seam Treatment

Seam Treatment

Isolation tape: butyl tape

Seam Treatment
Seam Treatment

4.7 Edge sealing treatment (particularly important during project construction)

Edge sealing treatment (particularly important during project construction)

4.8 Treatment of water inlets and pipe roots

Treatment of water inlets and pipe roots

4.9 Construction process of concrete base course

Construction process of concrete base course
Construction process of concrete base course

Follow-up visit after one year of use

Follow-up visit after one year of use

4.10 Construction process of metal substrate (steel substrate)

Construction process of metal substrate (steel substrate)
Construction process of metal substrate (steel substrate)

Two-component Spray Polyurea Material System

05 Acceptance

5.1 Material Inspection Upon Arrival

Table 7.1.3 Sampling and Re-inspection Items for Incoming Materials
Serial NumberMaterial NameSampling BatchSampling QuantityInspection Items
1Sprayed rapid-set urea coatingEach 15 tons constitute one batch. If the quantity is less than 15 tons, it should also be counted as one batch.Total weight according to formula: 40kgSolid content, tensile strength, elongation at break, impermeability
2Single-component slow-curing polyurea coating5kgSolid content, surface drying time, complete drying time, tensile strength, elongation at break, impermeability, thick coating blistering, bond strength under standard test conditions
3Two-component slow-curing polyurea coatingTotal weight according to formula: 5kgSolid content, surface drying time, tensile strength, elongation at break, impermeability, bond strength under standard test conditions
4Base coat and puttyCount 5 tons as one batch. Any quantity less than 5 tons should also be counted as one batch.Total weight according to formula: 1kgSurface drying time, bond strength on dry substrate, peel strength on dry substrate
5Coating with weather-resistant waterproofing paintIt should be counted as one batch for every 10 tons. If the quantity is less than 10 tons, it should also be regarded as one batch.2 kgSolid content, bond strength, impermeability
6Polyurethane building sealantCount 5 tons as one batch. Any quantity less than 5 tons should also be counted as one batch.1. Single component: 6 vials; 2. Two-component: Total weight according to formula: 4kgLeveling properties, surface drying time, adhesion at constant elongation, adhesion at constant elongation after immersion in water
7Tissue matrix reinforcing materialCount by 5,000 square meters as one batch. If the area is less than 5,000 square meters, it should also be counted as one batch.2㎡Mass per unit area

5.2 On-site Inspection

Table 7.3.1 Quality Requirements for the Base Layer
ItemQuality RequirementsTesting FrequencyTesting Methods
Adhesion strength between the repaired area and the substrate (MPa)≥2.0 or damaged concrete substrateEach 500㎡ should constitute one inspection batch, and each inspection batch should include at least 3 testing sites.Current Industry Standard: Technical Specification for On-site Testing of Building Waterproofing Engineering (JGJ/T 299) Test for Tensile Bond Strength of Substrate Surface
PrimerEven application, normal curing, no missed areas, no buildupVisual Inspection

7.3.2 After the surface treatment at the base layer is completed, it should be clean without any defects such as holes, hollowing, looseness, cracks, dust, oil stains, or foreign objects.
Testing method: Observation and inspection, as well as review of the acceptance records for concealed works.

5.3 Acceptance of Polyurea Coating

Acceptance of Polyurea Coating

7.4.3 Underground waterproofing projects using polyurea coatings should be inspected and accepted in accordance with the waterproofing grade standards specified in the design documents. Other waterproofing and protection projects must not have any leakage.
Testing method: Observation after rain or water immersion for 2 hours, and water retention test for 24 hours.

Two-component Spray Polyurea Material System

06 Case Analysis

Case 1: Construction requires specialization

What are the problems in the spraying process shown in the video

What are the problems in the spraying process shown in the video?

Issues:
1. Upwind spraying - - - Particulate matter pollution on the primer;
2. The distance between the spray gun and the base layer is too far - - - 0.5 meters;
3. Inclined spraying - - - Vertical spraying;
4. Unidirectional spraying - - - Crossed horizontally and vertically;

5. Coating lap risk - - - Spray in sequence.

What are the problems in the spraying process shown in the video

Reason:
One-way spraying, with poor horizontal and vertical coverage;
2. The environment is dirty, with debris on the floor.

Reason:
The details were not handled properly.

Reason:
The base concrete was not stable and cracks appeared.
2. The gap was not dealt with.

Case 2: Poor foundation condition, construction on the backside of the structure; materials and techniques were not mature.

Case 2: Poor foundation condition, construction on the backside of the structure; materials and techniques were not mature.

Case 3: Poor foundation condition, construction on the backside of the water surface

Poor foundation condition, construction on the backside of the water surface

Case 4: Particulate Matter Pollution

Particulate Matter Pollution

Case 5: Formation of Bulges

Formation of Bulges

Case 6: Equipment bias pressure, influence of a single material

Equipment bias pressure, influence of a single material

Case 7: The Impact of Inconsistent Material Mixing

The Impact of Inconsistent Material Mixing

Case 8: Formation of Pimple-like Lumps

Formation of Pimple-like Lumps

Case 9: Deception and Trickery

This is the reason why it is cheap.

Deception and Trickery
Deception and Trickery

Two-component Spray Polyurea Material System

07 Market quotation

The thickness of polyurethane

The thickness of polyurethane

Common thicknesses: 1.5mm, 2.0mm

Wear resistance thickness: 3 - 5mm

Two-component Spray Polyurea Material System

08 Closing Remarks

"Spraying polyurea" is never just referring to several materials or a few formulas; rather, it is an integrated application technology that combines materials, equipment, processes, and construction methods.

Discarding the aspects of equipment, process and construction and merely focusing on the polyurethane material is a manifestation of irresponsibility.